(1S,2S,3R,4R,6S)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside - Names and Identifiers
Name | D-chiro-Inositol, 1,5,6-trideoxy-3-O-beta-D-glucopyranosyl-
|
Synonyms | valimon VALIDACIN VALIDAMYCIN Validamycin Validamycin A VALIDAMYCIN A D-chiro-Inositol, 1,5,6-trideoxy-3-O-beta-D-glucopyranosyl- (1s-(1alpha,4alpha,5beta,6alpha))-1,5,6-trideoxy-4-o-beta-d-glucopyrano ((4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexen-1-yl)amino)-,(1s-(1-alpha,4 (1s-(1a,4a,5b,6a))-1,5,6-trideoxy-3-o-b-d-glucopyranosyl-5-(hydroxymethyl)-1-( 2,3-dihydroxy-6-(hydroxymethyl)-4-{[4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl hexopyranoside D-1,5,6-Trideoxy-3-O-beta-D-glucopyranosyl-5-
(hydroxymethyl)-1-((4,5,6-trihydroxy-3-(hydroxymethyl)-2-
cyclohexen-1-yl)amino)-D-chiroinositol D-Chiro-Inositol,1,5,6-trideoxy-4-O-b-D-glucopyranosyl-5-(hydroxymethyl)-1-[[(1S,4R,5S,6S)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexen-1-yl]amino]- (1S,2S,3R,4R,6S)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside (1S-(1a,4a,5B,6a))-1,5,6-Trideoxy-3-O-B-D-glucopyranosyl-5-
(hydroxymethyl)-1-((4,5,6-trihydroxy-3-(hydroxymethyl)-2-
cyclohexen-1-yl)amino)-d-chiro-inositol (1R,2R,3S,4S,6R)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(1S,4R,5S,6S)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside (1S-(1alpha,4alpha,5beta,6alpha))-1,5,6-trideoxy-4-O-beta-D-
glucopyranosyl-5-(hydroxymethyl)-1-((4,5,6-trihydroxy-3-
(hydroxymethyl)-2-cyclohexen-1-yl)amino)-D-chiro-inositol
|
CAS | 37248-47-8
|
EINECS | 609-372-4 |
InChI | InChI=1/C20H35NO13/c22-3-6-1-8(12(26)15(29)11(6)25)21-9-2-7(4-23)19(17(31)13(9)27)34-20-18(32)16(30)14(28)10(5-24)33-20/h1,7-32H,2-5H2 |
(1S,2S,3R,4R,6S)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside - Physico-chemical Properties
Molecular Formula | C20H35NO13
|
Molar Mass | 497.49 |
Density | 1.69±0.1 g/cm3(Predicted) |
Melting Point | 130-135°C |
Boling Point | 813.7±65.0 °C(Predicted) |
Specific Rotation(α) | D24 +110° (c = 1 in water or pyridine), +92° (c = 1 in DMF) |
Flash Point | 445.885°C |
Water Solubility | Readily soluble |
Solubility | Soluble in water, methanol, DMF,DMSO; Insoluble in acetone, ethanol and ether. |
Vapor Presure | Neglible at room temperature |
Appearance | White solid |
pKa | 6.0(at 25℃) |
Storage Condition | 0-6°C |
Refractive Index | 1.689 |
Physical and Chemical Properties | Pure white crystals, without a certain melting point, 130~135 C decomposition. Strong hygroscopicity, soluble in methanol, dioxane, dimethylformamide, insoluble in acetone, ethanol, insoluble in ether, benzene, chloroform, carbon tetrachloride, aldehyde acid ethyl ester and other organic solvents, soluble in water. In the pH value of 4~5 is more stable, in 0.2mol/L sulfuric acid 105 C, 10h decomposition, can be inactivated by a variety of microbial decomposition. |
Use | This product is for scientific research only and shall not be used for other purposes. |
(1S,2S,3R,4R,6S)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside - Reference
Reference Show more | 1. Hu Xuefang, Tian Zhiqing, Liang Liang, Zhu Xiangmin, Jiang Hao Ye, Wang Shikui, Pei Haisheng. Inhibitory effect of iodine (CCOS-I) from carboxylated chitooligosaccharides on Rhizoctonia solani and its mechanism [J]. Chinese Journal of Tropical Crops, 2018,39(08):1590-1595. 2. [IF = 4.845] Zhi-Jun Zhang et al."Design, synthesis, fungidal property and QSAR studies of novel β-vectors containing urea, benzoylthiourea and benzoylurea for the control of rice" sheath blight."Pest Manag Sci. 2018 Jul;74(7):1736-1746 3. [IF=5.645] Lantu Xiong et al."Microemulsification of nonvolatile components of Melaleuca alternifolia and borneol can effectively defend Rhizoctonia solani."INDUSTRIAL CROPS AND PRODUCTS. 2022 Sep;184:115052 |
(1S,2S,3R,4R,6S)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside - Nature
Open Data Verified Data
- pure white amorphous powder, without a certain melting point. Soluble in water, soluble in methanol, dioxane, dimethylformamide, ethanol-soluble, insoluble in acetone, benzene, petroleum ether. Strong moisture absorption. Weakly alkaline. Stable in neutral medium and weak acid, weak base at room temperature, easy to decompose in strong acid, alkali medium.
- The single dosage form is mainly soluble powder and water, and there are many kinds of compound preparations.
Last Update:2024-01-02 23:10:35
(1S,2S,3R,4R,6S)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside - Preparation Method
Open Data Verified Data
It is prepared from the fermentation extraction of water-absorbing streptomycin Jinggang variety. Process flow: Sand soil pipe mother inclined eggplant bottle seed tank fermentation tank put tank
Last Update:2022-01-01 11:18:50
(1S,2S,3R,4R,6S)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside - Introduction
Jinggangmycin is an antibiotic produced by actinomycetes. It has strong absorption and is easily absorbed by bacterial cells and rapidly conducted in it, interfering with and inhibiting the growth and development of bacterial cells. Selective antibiotic fungicides. It has special effects on the prevention and control of rice sheath blight, and can also be used for the prevention and control of rice smut, wheat sheath blight, vegetable blight and root rot, cotton; legume blight, rice sclerotinia sclerotiae, and corn large spot. is an antibiotic that inhibits trehalase activity in plants, insects and fungi and causes the accumulation of trehalose in transgenic plants.
Last Update:2022-10-16 17:24:57
(1S,2S,3R,4R,6S)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside - Use
Open Data Verified Data
microbial source fungicides, mainly used for the prevention and control of rice sheath blight, both protective and therapeutic effects, and the treatment of small grain Sclerotinia sclerotiorum, corn leaf blight, vegetable blight and root rot, cotton, beans, ginseng seedling blight, etc. Spray, seed dressing and soil filling can be used. It can be mixed with pesticide such as dimethoate and pyridin.
Last Update:2022-01-01 11:18:51
(1S,2S,3R,4R,6S)-2,3-dihydroxy-6-(hydroxymethyl)-4-{[(4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino}cyclohexyl beta-D-glucopyranoside - Safety
Open Data Verified Data
- pure mice acute oral LD50>20000mg/kg, intravenous LD50 >13000mg/kg. It is a low toxicity fungicide, but still need to pay attention to personal safety, if poisoning, no specific antidote, should be symptomatic treatment.
- during transportation, care must be taken to ensure that it is not inverted, and collision and heavy pressure are avoided. Storage and Transportation, must be strictly protected from sun, moisture, and maintain good ventilation, placed in a dry and cool place.
Last Update:2022-01-01 11:18:51